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RMIT University study shows that adding copper strengthens 3D printed titanium

Could lead to new range of high-performance alloys for medical and aerospace applications

Copper has been hot in 3D printing recently and titanium has been hot from the start of the metal AM industry. Now a study on a new titanium copper alloy, published in Nature Journal by RMIT researchers, combines the two materials in order to reduce the risk of cracking and deformation.

Current titanium alloys used in additive manufacturing often cool and bond together in column-shaped crystals during the 3D printing process, making them prone to cracking or distortion. And unlike aluminum or other commonly used metals, there is no commercial grain refiner for titanium that manufacturers can use to effectively refine the microstructure to avoid these issues.

Professor Mark Easton from RMIT University’s School of Engineering said their titanium–copper alloy printed with “exceptional properties” without any special process control or additional treatment. Successful trials of titanium-copper alloys for 3D printing could kickstart a new range of high-performance alloys for medical device and aerospace applications.

“Of particular note was its fully equiaxed grain structure: this means the crystal grains had grown equally in all directions to form a strong bond, instead of in columns, which can lead to weak points liable to cracking. Alloys with this microstructure can withstand much higher forces and will be much less likely to have defects, such as cracking or distortion, during manufacture,” Easton said.

The collaborative project involved leading researchers in the area of alloy composition and grain microstructure from RMIT University, CSIRO, the University of Queensland and the Ohio State University.

titanium copper alloy
A 3D-printed titanium-copper block made at RMIT’s Advanced Manufacturing Precinct.

CSIRO Senior Principal Research Scientist, Dr Mark Gibson, said their findings also suggest similar metal systems could be treated in the same way to improve their properties. “Titanium-copper alloys are one option, particularly if the use of other additional alloying elements or heat treatments can be employed to improve the properties further,” he said. “But there are also a number of other alloying elements that are likely to have similar effects. These could all have applications in the aerospace and biomedical industries.”

Gibson said the new breed of alloys could increase manufacturers’ production rates and allow for more complex parts to be manufactured.  “In general, it opens up the possibility of developing a new range of titanium-based alloys specifically developed for 3D printing with exceptional properties,” he said.

“It has been a delight, as it has been my good fortune for some time, to work on such an interesting and significant project as this with such a talented band of scientists,” Gibson said.

The work was part of a project funded by the Australian Research Council. The study ‘Additive manufacturing of ultrafine-grained high-strength titanium alloys’ is published in Nature with DOI 10.1038/s41586-019-1783-1

titanium copper alloy
RMIT researchers involved in the multi-partner collaboration: Dr Dong Qiu, Professor Mark Easton and Dr Duyao Zhang.
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Davide Sher

Since 2002, I have built up extensive experience as a technology journalist, market analyst and consultant for the additive manufacturing industry. Born in Milan, Italy, I spent 12 years in the United States, where I received my Bachelor of Arts undergraduate degree. As a journalist covering the tech industry - especially the videogame industry - for over 10 years, I began covering the AM industry specifically in 2013, as blogger. In 2016 I co-founded London-based 3D Printing Business Media Ltd. (now 3dpbm) which operates in marketing, editorial, and market analysis & consultancy services for the additive manufacturing industry. 3dpbm publishes 3D Printing Business Directory, the largest global directory of companies related to 3DP, and leading news and insights websites 3D Printing Media Network and Replicatore. I am also a Senior Analyst for leading US-based firm SmarTech Analysis focusing on the additive manufacturing industry and relative vertical markets.

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